Coordination Chemistry of Bidentate Ligands Research

Coordination Chemistry of Bidentate Ligands ResearchElham Torabi FarkhaniMehrdad PourayoubiPavel V. AvdreevKatarina foundingThe coordination chemistry of bidentate ligands has been studied for over thirty years reference. The bidentate ligands with phosphoryl and thiophosphoryl groups have been used as effective coordinating agents in the several(predicate) surface chemistry, in most cases the reports were attributed to bonding between the metal cation and specific Lewis sites on the ligand, itself has number sites with potential to bind metal ions, such as nitrogen, sulfur and oxygen. In order to recent report Hg metal ion is known to have strong affinity for nitrogen and sulfur Lewis sites reference which our work up here is d iodin bonding between Hg metal jot and sulfur in ligands. A search of the Cambridge Structural Database (CSD) reference yielded a entropy set of 76 purely molecular structures to be used for believe of coordination of metal atom with a P(S)NO2 skeleto n of ligand. Thus there atomic number 18 a number of reports on molecular structure contain M-S=P fragments with different metal atoms reference. An investigation of the reports reveals that there isnt any number with Hg metal, also we havent found any microscopic study on the effect of all interactions, including coordinating linkages and intermolecular interactions on the structure of Hg(II) convolutedes with bisthiophosphoryl ligands. Accordingly we have carried out a study on mercury (II) chloride with two different bidentate ligand with general formula (OEt)2P(S)-X-P(S)(OEt)2 where X=1,4-NH-C6H5-NH and piperazine (scheme ). Reaction of two ligand with HgCl2 leaved binu put one across convoluted C1 and C2. All compounds were charactrized by IR and proton magnetic resonance (1H, 13C and 31P nuclear magnetic resonance) spectroscopy and stack analysis. The structure of ligand 1 and two tangledes C1 and C2 were set(p) by X-ray watch crystallography.ExperimentalMaterials a nd methodsMercuric chloride (99.5%), O,O-diethyl chlorothiophosphate (OCH2CH3)2P(S)Cl (97%), diethylenediamine (97%), 1,4-phenylenediamine (99%) (Aldrich), acetonitrile (99%) and methanol (99%) (Merck) were used as supplied. Acetonitrile was dried with P2O5 and distilled prior to use. The 1H, 13C and 31P NMR spectra were recorded on a Bruker bestride 400 spectrometer at 400, 101 and 162 MHz, respectively. 1H chemical shifts were determined sex act to Si (CH3)4. 31P chemical shift was measured relative to 85% H3PO4 as external standard. big money spectra were performed using a Varian Star 3400 CX cumulation spectrometer. Infr atomic number 18d (IR) spectra were recorded on KBr disk using a take 500 scientific spectrometer. Elemental analysis was performed using a Thermo Finnigan ignite EA 1112 apparatus. X-ray selective in defining show was performed with a Xcalibur, Sapphire3, Gemini diffractometer with graphite monochromator. deductionGeneral procedure for the preparation of ligandsThe ligands were synthesized from the reaction of 2 mmol (OCH2CH3)2P(S)Cl with 1 mmol of the alike(p) diamine (diethylenediamine and 1,4-phenylenediamine) in presence of Et3N as HCl scavenger in CH3CN at 0 C. After stir work party for 24 h, the solvent was evaporated and the residue was washed with distilled irrigate and dried. Chemical structures are shown in scheme 1. Physical and spectroscopic selective information of the ligands are presented below1, 4 (C2H5O)2P(S)N2C4H8 (L1) Mp one hundred five C. Anal. calc. (%) for C12H28N2O4P2S2 C 36.88 H 7.17 N 7.17, S 16.39, found C 37.81 H 7.16, N 7.26, S 15.7. IR data (KBr, cm-1) 2990, 2903, 2864, 1449, 1387, 1339, 1264, 1151, 1098, 1029, 972, 792, 714.1H NMR (400 MHz, DMSO-d6) 1.22 (t,3JH-H= 7.1 Hz, 12H, CH3), 3.12 (m, 8H, C4H8), 7.00 (m, 8H, CH2), 13C NMR (101 MHz, DMSO-d6) 15.57 (d, 3JP-C = 8.08 Hz, 4C, CH3), 44.84 (s, 4C, C4H8), 62.45 (s, 4C, CH2), 31P NMR (162 MHz, DMSO-d6) 73.64. MS (70 eV, EI) m/z (%) = 390 (28), 23 5 (43), 195 (100), 153 (99), 120 (96), 96 (100), 28 (66).1, 4 (C2H5O)2P(S)NH2C6H4 (L2) Mp 105 C. Anal. calc. (%) for C14H26N2O4P2S2 C 40.73, H 6.30, N 6.78, S 15.51, found C 41.15, H 6.34, N 7.01, S 15.57. IR data (KBr, cm-1) 3268, 2980, 1515, 1479, 1380, 1278, 1218, 1168, 1023, 959, 816, 726, 646. 1H NMR (400 MHz, CD3CN) 1.22 (t,3JH-H= 7.1 Hz, 12H, CH3), 3.12 (m, 8H, C4H8), 7.00 (m, 8H, CH2), 13C NMR (101 MHz, CD3CN) 15.57 (d, 3JP-C = 8.08 Hz, 4C, CH3), 44.84 (s, 4C, C4H8), 62.45 (s, 4C, CH2), 31P NMR (162 MHz, CD3CN) 73.64. MS (70 ev, EI) m/z (%) = 412 (94), 411 (100), 168 (26), 107 (89), 96 (91), 92 (39), 65 (87), 28 (88).General procedure for the preparation of complexesThe complexes were prepared by a solutions of 2 eq. HgCl2 in 15 ml of methanol was added drop wise to a solution of 1 eq. the corresponding ligand in 15 ml of methanol. The clear solution was stirred under reflux for 24h. Crystals suitable for X-ray diffraction were obtained from long-winded evaporation of t he solution at room temperature. Physical and spectroscopic data of the complexes are given below-1, 4-(C2H5O)2P(S)N2C4H8(HgCl2)2 (C1) Mp 105 C. Anal. calc. (%) for C12H28Cl4Hg2N2O4P2S2 C 15.41 H 2.99 N 2.99, S 6.84, found C 15.67 H 2.91, N 2.99, S 5.74. IR data (KBr, cm-1) 2976, 2895, 1444, 1383, 1344, 1266, 1121, 1037, 967, 804, 772, 702.1H NMR (400 MHz, CD3CN) 1.22 (t,3JH-H= 7.1 Hz, 12H, CH3), 3.12 (m, 8H, C4H8), 7.00 (m, 8H, CH2), 13C NMR (101 MHz, CD3CN) 15.57 (d, 3JP-C = 8.08 Hz, 4C, CH3), 44.84 (s, 4C, C4H8), 62.45 (s, 4C, CH2), 31P NMR (162 MHz, CD3CN) 73.64.-1, 4 -(C2H5O)2P(S)NH2C6H4(HgCl2)2 (C2) Mp 105 C. Anal. calc. (%) for C14H26Cl4Hg2N2O4P2S2 C 17.59 H 2.72 N 2.93, S 6.70, found C 17.85 H 2.69, N 2.93, S 6.53. IR data (KBr, cm-1) 3211, 2990, 1615, 1512, 1479, 1380, 1274, 1214, 1161, 988, 824, 633. 1H NMR (400 MHz, CD3CN) 1.22 (t,3JH-H= 7.1 Hz, 12H, CH3), 3.12 (m, 8H, C4H8), 7.00 (m, 8H, CH2), 13C NMR (101 MHz, CD3CN) 15.57 (d, 3JP-C = 8.08 Hz, 4C, CH3), 44.84 (s, 4 C, C4H8), 62.45 (s, 4C, CH2), 31P NMR (162 MHz, CD3CN) 73.64.Result and discussionIR and NMR spectroscopyMass spectroscopyThe nature of the fragments observed in the mass spectrum often provides as clue to the molecular structure. The fragmentation pathways of ligands 1 and 2 were studied by electron ionization at 70 eV experiment and revealed a molecular ion peak M+ at m/z (%) of 390 (28) and 412 (94) for 1 and 2, respectively. The formation of the M-1 specie from the parent ion of compound 2 was shown to exclusively involve an redolent heat content atom our results were in good agreement with previously make results. reference. The previous paper has been shown that dialkyl alkanephosphonates ROCH2CH2P(O)(OR)2 undergo a McLafferty rearrangement in which a hydrogen from the alkylphosphorous moiety migrates to the phosphoryl group and a mote of olefin is eliminated from the molecular ion reference. The mass spectra of compound 1 and 2 with the same structure have affirm previou sly reported mechanism. The peak related to the C2H4 radical-cation with m/z = 28 are shown for two structures. Relative peak height = relative teemingness as measured from this ion in the compound 1 and 2 are 66 and 88.For the compound 1, the base peak is appeared at m/z = 153 (P(S)(OEt)2) and in the compound 2, the base peak is appeared at m/z = 411 (M-1) fragment. For 1, the main fragmentation is based cleavage of N-P bond thus produced A ion and P(S)(OEt)2 with m/z 153. The ion of A following three pathways (1) A ion notify produce a stabilized ion by loss of ethylene via the McLafferty rearrangement which generate the odd mass ion m/z 181 that it operates for ion m/z 181 assailable of electronic shift involving a six-membered cyclic transition enjoin in the particle skeleton given in scheme 1. This result then stabilize to an even mass ion m/z one hundred eighty by elimination of an H radical. (2) in this pathway produce the ion at m/z 147 that formed through a three- mem bered ring as transition state by loss of two blood corpuscle of ethanol. The ion of m/z 147 indicating the relatively low stability of the P-O bond to the particle of A in comparison with that of the P-N bond. (3). The ion at m/z 84 is formed through two step, the first is cleavage of P-N bond then in second step is formed via a 1,2 hydride shift by loss of a molecule of P(S)(OEt)2 reference. The same kind of rearrangement is observed for 2 and the main fragmentation is based cleavage of N-P bond then produced molecule ion with m/z 107.Scheme 1. Fragmentation pathway of compound 1X ray crystallographyComplexes of 1 and 2 were crystallized in the orthorhombic quadriceps femoris group Pbca Triclinic with space group P, respectively. Crystal data, data battle array and structure refinement details are summarized in Table 1 and selected bond aloofnesss and angles are given in Tables 2 and 3.The asymmetric whole of complexes of 1 and 2 consist of one Hg2+ ion, two Cl and one half c rystallographically independent ligand (Fig 1). There are two different types of Hg-Cl bonds that include bridge Hg1-Cl2 bond (2.5904(17) in 1 and 2.4852 (7) in 2) connect the molecule into one dimensional bowed stringed instrument extended along the c axis vertebra and terminal Hg1-Cl1 bond (2.369(2) in 1 and 2.4295 (9) in 2) linked to adjoining ones by intermolecular interaction into a compass parallel to b axis in 1 and a axis in 2. (Fig 2). So, the Hg atom adopts an HgCl3S coordination environment in this compound with the highly distorted tetrahedral geometry of the Hg(II) meaning that can be better described as a paddle structure which two chloride atoms and Hg atom Hg1, Hg1, Cl2 is planar, one chloride and sulfur atoms in the pivot position. The different bond distance from the -chloride atoms performed and refer to asymmetry of the halogen bonds (2.5904 (17), 2.6820 (17) in 1 and 2.4852 (7), 2.8273 (8) in 2) and they are compared to the terminal bond of Hg-Cl sl ightly extended. rough selected bond angles specify the distorted tetrahedral geometry at the Hg(II) center in complex 1 are as follows Cl1Hg1S1 130.91 (7), Cl1Hg1Cl2 110.98 (7), S1Hg1Cl2 104.59 (6), Cl1Hg1Cl2i 108.29 (8), S1Hg1Cl2i 105.96 (6) , Cl2Hg1Cl2i 87.47 (5), Hg1Cl2Hg1i 92.54 (5) and P1S1Hg1 98.40 (8).In ligand L1, the phosphorus atom has a distorted tetrahedral NP(S)O2 configuration with the bond angles in the range of 101.77 (18) O2P1S1 to 115.80 (19) O1P1S1. The P=S bonds of ligand are in a trans orientation is showing respect to separately other and that the sulfur atom is coordinated to the mercury center. As a result of coordination to the mercury center, as expected, the P=S bond length (P (1)S (1) 1.97 (9) ) is slightly longer than that of the free ligandThe crystal structure of the complex 1 generated by the O1S=P interaction along c-axis. As a result of these interactions, One-dimensional chain structure is produced. The presence of Hg-Cl and Hg-S moieties in the complex lead to the formation weaker intermolecular C-HCl-Hg , C-HS-Hg interactions between the neighboring 1D chain along b-axis that create a two-dimensional array in the crystal lattice.Scheme 2. Schematic presentation of bisthiophosphoryl ligands 1 (right), 2 (left)Fig. 1 asymmetric unit of complex 1(right) and 2 (left) are shownFig.2 Representation of one-dimensional chain of complex 1 along the c-axis. Colour keys for the atoms Hg ., P orange, O red, N blue, C light grey, H light blueFig. 3 The title complex 1, with displacement ellipsoids drawn at the 50% opportunity levelFig. 4 The title complex 2, with displacement ellipsoids drawn at the 50% probability levelTable 1. Crystal data, data collection and refinement for complexes 1 and 2Table 2 Selected bond lengths (A) and angles () for complex 1Table 3 Selected bond lengths (A) and angles () for complex 2